Networks
McBride, Murray B
Cornell Faculty Member
Close
Positions
My long-term interests focus on understanding the behavior of contaminants at the soil-water interface in the environment, with particular emphasis on the phytotoxic and zootoxic trace and heavy metals. In order to understand adsorption and degradation processes mechanistically, I use numerous methods such as spectroscopy to investigate speciation and bonding of metal ions and organic molecules at surfaces and in soil solution. I have interest in the issue of soil health, as it is impacted by the contamination of soils by various waste materials, commercial fertilizers and manures.
Research Areas
- biogeochemistry
- ecosystem biology
- environmental sciences
- nanotechnology
- soil and crop science
- soil health
- toxicology
- urban environment
- waste management
- Affiliations
- Extension
- Research
- Publications
- Teaching
- Service
- Background
- Other
- View All
Affiliations
Extension
has primary specialization area
Research
research overview
- The focus of my research at present is the bioavailability of toxic and trace metals in soils to crops, animals, and humans, considering all of the properties of soils that modify this bioavailability. Ultimately, this research has several goals, protecting food crops from toxic metal contaminants, minimizing trace element deficiencies, and developing methods for testing and remediating contaminated soils.
research activities
principal investigator on
area(s) of concentration/expertise
keywords
- chemistry of trace and toxic metals in soils
- soil health
- surface chemistry of minerals
submitted impact statement
Publications
individual publications
-
academic article
- A comparison of screening tests for soil Pb. Soil Science Journal. 177:650-654. 2012
- Degradation of ciprofloxacin by cryptomelane-type manganese ( III/IV) oxides. Enviromental Science and Pollution Research. 20:10-21. 2012
- Influence of compost addition on lead and arsenic bioavailability in reclaimed orchard soil assessed using Porcellio scaber bioaccumulation test. Journal of Hazardous Materials. 205-206:144-149. 2012
- Lead and arsenic uptake by leafy vegetables grown on contaminated soils: Effects of mineral and organic amendments. Water, Air, and Soil Pollution. 224:1378. 2012
- A comparison of reliability of soil cadmium determination by standard spectrometric methods. Journal of Environmental Quality. 40:1863-1869. 2011
- Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresource Technology. 102:8877-8884. 2011
- Chemical Extractability of Pb in Field-Contaminated Soils : Implications for Estimating Total Pb.. Communications in Soil Science and Plant Analysis. 75:1581-1593. 2011
- A Comparison of Tests for Extractable Copper and Zinc in Metal-Spiked and Field-Contaminated Soil. Soil Science Journal. 174:439-444. 2009
- Cadmium uptake from soil by maize with intercrops. Water, Air, and Soil Pollution. 199:45-56. 2009
- Effect of MSW source-classified collection on polycyclic aromatic hydrocarbons in residues from full-scale incineration in China. Water, Air, and Soil Pollution. 198:347-358. 2009
- Health risk from heavy metals via consumption of food crops in the vicinity of Dabaoshan mine, South China. Science of the Total Environment. 407:1551-1561. 2009
- Phytotoxic Effects of Cu and Zn on Soybeans Grown in Field-aged Soils: Their Additive and Interactive Actions. Journal of Environmental Quality. 38:2253-2259. 2009
- Reduction of nitrogen loss and Cu and Zn mobility during sludge composting with bamboo charcoal amendment. Environmental Science & Pollution Research. 16:1-9. 2009
- Urease Activity in Aged Copper and Zinc-Spiked Soils: Relationship to CaCl2-extractable Metals and Cu(2+) Activity. Environmental Toxicology and Chemistry. 27:2469-2475. 2009
- Aging effects on partitioning coefficients of Cd, Cu and Zn in metal-spiked soils. Journal of Korean Society of Soil and Ground water Environment. 13:47-56. 2008
- Biomass and Cu and Zn uptake of two turfgrass species grown in sludge compost-soil mixtures. Water Air and Soil Pollution. 188:224-234. 2008
- Effect of composting on polycyclic aromatic hydrocarbons removal in sewage sludge. Water Air and Soil Pollution. 193:259-267. 2008
- Urease activity in aged copper and zinc-spiked soils: relationship to CaCl2 –extractable metals and Cu2+ activity. Environmental Toxicology and Chemistry. 27:2469-2475. 2008
- Dissolution of zinc-cadmium sulfide solid solutions in aerated aqueous suspensions. Soil Science Society of America Journal. 71:322-328. 2007
- Phosphate and glyphosate mobility in soil columns amended with Roundup. Soil Science Journal. 172:17-26. 2007
- The long-term effect of sludge application on Cu, Zn, and Mo behavior in soils and accumulation in soybean seeds . Plant and Soil. 299:227-236. 2007
- Trace metals and sulfur in soils and forage of a chronic wasting disease locus. Environmental Chemistry. 4:134-139. 2007
- A test of sequential extractions for determining metal speciation in sewage sludge-amended soils . Environmental Pollution. 144:475-482. 2006
- A voltammetric method for determining free metal activities in aqueous solutions. Part 1: direct current voltammetry of Cd, Cu, and Pb. International Journal of Environment and Pollution. 26:41-67. 2006
- A voltammetric method for determining free metal activities in aqueous solutions. Part 2: anodic stripping voltammetry of Cd, Cu, Pb and Zn in synthetic and soil solutions. International Journal of Environment and Pollution. 26:68-89. 2006
- Cadmium sorption in soils 25 years after amendment with sewage sludge. Soil Science Journal. 171:21-28. 2006
- Copper and zinc accumulation in dairy and poultry amended soils. Soil Science Journal. 171:388-399. 2006
- Trace element mobilization in soils by glyphosate. Soil Science Society of America Journal. 70:1882-1888. 2006
- Zinc and cadmium distribution and leaching in a metalliferous peat. Water, Air, and Soil Pollution. 171:67-80. 2006
- Environmental factors determining the trace-level sorption of silver and thallium to soils. Science of the Total Environment. 345:191-205. 2005
- Molybdenum and copper uptake by forage grasses and legumes grown on a metal-contaminated sludge site. Communications in Soil Science and Plant Analysis. 36:2489-2501. 2005
- Oxidative degradation of glyphosate and aminomethylphosphonate by manganese oxide. Environmental Science & Technology. 39:9223-9228. 2005
- Reduction of silver solubility by humic acid and thiol ligands during acanthite (beta-Ag2S) dissolution. Environmental Pollution. 135:1-9. 2005
- The desorption of silver and thallium from soils in the presence of a chelating resin with thiol functional groups. Water, Air, and Soil Pollution. 160:41-54. 2005
- Bioavailability and crop uptake of trace elements in soil columns amended with sewage sludge products. Plant and Soil. 262:71-84. 2004
- Coprecipitation of trace metal ions during the synthesis of hectorite. Applied Clay Science. 27:129-140. 2004
- Environmental Impacts of Applying Manure, Fertilizer, and Sewage Biosolids on a Dairy Farm. Journal of American Water Resources Association. 40:1025-1042. 2004
- Lead phosphate minerals: Solubility and dissolution by model and natural ligands. Environmental Science & Technology. 38:5584-5590. 2004
- Microbial acidification and pH effects on trace element release from sewage sludge. Environmental Pollution. 132:61-71. 2004
- Molybdenum extractability in soils and uptake by alfalfa 20 years after sewage sludge application. Soil Science Journal. 169:505-514. 2004
- Molybdenum, sulfur and other trace elements in farm soils and forages after sewage sludge application. Communications in Soil Science and Plant Analysis. 35:517-535. 2004
- Aging and temperature effects on DOC and elemental release from a metal contaminated soil. Environmental Pollution. 122:135-143. 2003
- Cadmium concentration limits in agricultural soils: weaknesses in USEPA’s risk assessment and the 503 rule. Human and Ecological Risk Assessment. 9:661-674. 2003
- Chloride and lithium transport in large arrays of undisturbed silt loam and sandy loam soil columns. Vadose Zone Journal. 2:715-725. 2003
- Effect of microbial activity on trace element release from sewage sludge. Environmental Science & Technology. 37:3361-3366. 2003
- Temperature and Microbial Activity Effects on Trace Element Leaching from Metalliferous Peats. Journal of Environmental Quality. 32:2067-2075. 2003
- Temperature and activity effects on trace element leaching from metalliferous peat. Journal of Environmental Quality. 32:2067-2075. 2003
- Toxic metals in sewage sludge-amended soils: has promotion of beneficial use discounted the risks?. Advances in Environmental Research. 8:5-19. 2003
- Trace medal accumulation by red clover grown on sewage sludge-amended soils and correlation to Mehlich 3 and calcium chloride-extractable metals. Soil Science Journal. 168:29-38. 2003
- Cadmium uptake by crops estimated from soil total Cd and pH. Soil Science Journal. 167:62-67. 2002
- Diffuse double-layer models, long-range forces, and ordering in clay colloids. Soil Science Society of America Journal. 66:1207-1217. 2002
- Trace metal extractability in soils and uptake by bromegrass 20 years after sewage sludge application. Canadian Journal of Soil Science. 82:323-333. 2002
- Zinc-sulfur and cadmium-sulfur association in metalliferous peats: Evidence from spectroscopy, distribution coefficients, and phytoavailability. Environmental Science & Technology. 36:3683-3689. 2002
- Effect of sludge processing mode, soil texture and soil pH on metal mobility in undisturbed soil columns under accelerated loading.. Environmental Pollution. 109:327-346. 2000
- Molybdenum uptake by forage crops grown on sewage sludge-amended soils in the field and greenhouse. Journal of Environmental Quality. 29:848-854. 2000
- Land Application of Sewage Sludges: An Appraisal of the US Regulations. International Journal of Environment and Pollution. 11:1-36. 1999
- Long-Term Leching of Trace Elements in a Heavily Sludge-Amended Silty Clay Loam Soil. Soil Science Journal. 164:613-623. 1999
- Trace metal retention in the incorporation zone of land-applied sludge. Environmental Science & Technology. 33:1171-1174. 1999
- Metal mobility at an old, heavily-loaded sludge application site. Environmental Pollution. 99:365-377. 1998
- Sludge effects on land: a case for caution. Resource [ASABE]. 5:11-12. 1998
- Mobility and solubility of toxic metals and nutrients in soil fifteen years after sludge application. Soil Science. 162:487-500. 1997
- Movement of heavy metals through undisturbed and homogenized soil columns. Soil Science. 16:740-750. 1996
-
article
-
chapter
- Attenuation of Metal Toxicity in Soils by Biological Processes. Natural Attenuation of Trace Element Availability in Soils. 113-136. 2007
- Neurodegenerative Diseases and the Environment. Health and the Planet. 31-50. 2005
-
conference poster
-
document part
-
report
- Manganese 2010
- Timing of Lime Applications for Field Crops 2010
- Case for Caution Revisited: Health and Environmental Impacts of Application of Sewage Sludges to Agricultural Land 2009
- Guide to Soil Testing and Interpreting Results 2009
- Sources and Impacts of Contaminants in Soils 2009
- Considerations for Dairy Farms Regarding Use of Sewage Sludges, Sludge Products and Septage 2003
- Sludge application 2000
- Sludge application 1997
- The Case for Caution 1997
featured in archived article
speaker at Cornell event
Teaching
teaching overview
- My teaching attempts to explain to students the chemical processes that go on the complex environment of soils by using simple physical chemical principles. I teach an undergraduate course in Environmental Chemistry, which covers important environmental topics in soils, the atmosphere, and the hydrosphere. This course uses case studies of pollution in the biosphere and considers the potential effects on soil, plant, animal and human health. Because new environmental issues are emerging every year as more is learned, lectures evolve in response to this dynamic situation. I also teach an advanced soil chemistry course, intended primarily for graduate students with a strong background in physical chemistry. This course covers the basic chemistry of clay mineralogy, soil organic matter, soil acidity, cation exchange, chemisorption of metal cations and oxyanions, redox processes and soil salinity.
teaching activities
- CSS-3650: Environmental Chemistry: Soil, Air, and Water - Spring 2013
- CSS-4990: Undergraduate Research - Spring 2013
- CSS-6980: Graduate Teaching or Extension Experience - Spring 2013
- CSS-7900: Graduate-Level Dissertation Research in Soil Science - Spring 2013
- CSS-7970: Graduate Individual Study in Crop and Soil Science - Spring 2013
- CSS-8920: Master's Level Thesis Research in Soil Science - Spring 2013
- CSS-9900: Doctoral-Level Dissertation Research in Soil Science - Spring 2013
- TOX-8900: Master's Thesis and Research - Spring 2013
- TOX-9900: Doctoral Thesis and Research - Spring 2013
- CSS-6710: Soil Chemistry - Fall 2012
- CSS-6980: Graduate Teaching or Extension Experience - Fall 2012
- CSS-7900: Graduate-Level Dissertation Research in Soil Science - Fall 2012
- CSS-7970: Graduate Individual Study in Crop and Soil Science - Fall 2012
- CSS-8920: Master's Level Thesis Research in Soil Science - Fall 2012
- CSS-9900: Doctoral-Level Dissertation Research in Soil Science - Fall 2012
- TOX-8900: Master's Thesis and Research - Fall 2012
- TOX-9900: Doctoral Thesis and Research - Fall 2012
- CSS-3650: Environmental Chemistry: Soil, Air, and Water - Spring 2012
- CSS-4990: Undergraduate Research - Spring 2012
- CSS-6980: Graduate Teaching or Extension Experience - Spring 2012
- CSS-7900: Graduate-Level Dissertation Research in Soil Science - Spring 2012
- CSS-7970: Graduate Individual Study in Crop and Soil Science - Spring 2012
- CSS-8920: Master's Level Thesis Research in Soil Science - Spring 2012
- CSS-9900: Doctoral-Level Dissertation Research in Soil Science - Spring 2012
- TOX-8900: Master's Thesis and Research - Spring 2012
- TOX-9900: Doctoral Thesis and Research - Spring 2012
- CSS-6710: Soil Chemistry - Fall 2011
- CSS-6980: Graduate Teaching or Extension Experience - Fall 2011
- CSS-7900: Graduate-Level Dissertation Research in Soil Science - Fall 2011
- CSS-7970: Graduate Individual Study in Crop and Soil Science - Fall 2011
- CSS-8920: Master's-Level Thesis Research in Soil Science - Fall 2011
- CSS-9900: Doctoral-Level Dissertation Research in Soil Science - Fall 2011
- TOX-8900: Master's Thesis and Research - Fall 2011
- TOX-9900: Doctoral Thesis and Research - Fall 2011
Service
outreach overview
- As part of my outreach activities as Director of the Cornell Waste Management Institute, I am involved in working with extension staff at Cornell in developing guidelines and publications on the management of waste products (composts, sewage products, fly ash, etc.) used in farms and gardens. Improved methods of testing contaminated soils for toxic metals such as lead, zinc, cadmium and copper, and interpreting these tests, is also a focus of my outreach effort. The goal is to provide urban gardeners with science-based information to minimize their exposure to toxic metals and other contaminants in soils.
Background
education and training
- Ph.D. in Soil Chemistry, Michigan State University 1974
- M.S. in Soil Chemistry, Michigan State University 1972
- University of Guelph 1971
awards and honors
Other
college
- CALS
research keyword
- chemistry of trace and toxic metals in soils
- soil health
- surface chemistry of minerals
name prefix
- Dr.